The kinetic theory of gases assumes that all gases behave ideally, but we know that’s not really what happens in the real world. For example, real gas particles do occupy space and also attract each other, although these properties are more apparent at lower temperature because usually the particles have enough kinetic energy to zip by each other without worrying about the attractive or repulsive charges from other molecules. If the molecules move slow enough though, they do get affected by the push or pull of other molecules.


Also at high pressures, the molecules are so tightly packed together that they do start to have volume considerations that need to be addressed. So for a real gas, we can make calculations like this:


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